3010. The Pauli Exclusion PrincipleLearning Objectives
MultipleElectron AtomsAll atoms except hydrogen are multipleelectron atoms. The physical and chemical properties of elements are directly related to the number of electrons a neutral atom has. The periodic table of the elements groups elements with similar properties into columns. This systematic organization is related to the number of electrons in a neutral atom, called the In 1925, the Austrian physicist Wolfgang Pauli (see Figure 1) proposed the following rule: No two electrons can have the same set of quantum numbers. That is, no two electrons can be in the same state. This statement is known as the Pauli Exclusion PrincipleNo two electrons can have the same set of quantum numbers. That is, no two electrons can be in the same state. Let us examine how the exclusion principle applies to electrons in atoms. The quantum numbers involved were defined in Quantum Numbers and Rules as $\mathrm{n,\; l,}\phantom{\rule{0.25em}{0ex}}{m}_{l}\mathrm{,\; s}$, and ${m}_{s}$. Since $s$ is always $1/2$ for electrons, it is redundant to list $s$, and so we omit it and specify the state of an electron by a set of four numbers $\left(n,\phantom{\rule{0.25em}{0ex}}l,\phantom{\rule{0.25em}{0ex}}{m}_{l},\phantom{\rule{0.25em}{0ex}}{m}_{s}\right)$. For example, the quantum numbers $\left(\mathrm{2,\; 1,\; 0,}\phantom{\rule{0.25em}{0ex}}1/2\right)$ completely specify the state of an electron in an atom. Since no two electrons can have the same set of quantum numbers, there are limits to how many of them can be in the same energy state. Note that $n$ determines the energy state in the absence of a magnetic field. So we first choose $n$, and then we see how many electrons can be in this energy state or energy level. Consider the $n=1$ level, for example. The only value $l$ can have is 0 (see Section 309 Table 1 for a list of possible values once $n$ is known), and thus ${m}_{l}$ can only be 0. The spin projection ${m}_{s}$ can be either $+1/2$ or $1/2$, and so there can be two electrons in the $n=1$ state. One has quantum numbers $\left(\mathrm{1,\; 0,\; 0,}\phantom{\rule{0.25em}{0ex}}+\mathrm{1/2}\right)$, and the other has $\left(\mathrm{1,\; 0,\; 0,}\phantom{\rule{0.25em}{0ex}}\mathrm{1/2}\right)$. Figure 2 illustrates that there can be one or two electrons having $n=1$, but not three. Shells and SubshellsBecause of the Pauli exclusion principle, only hydrogen and helium can have all of their electrons in the $n=1$ state. Lithium (see the periodic table) has three electrons, and so one must be in the $n=2$ level. This leads to the concept of shells and shell filling. As we progress up in the number of electrons, we go from hydrogen to helium, lithium, beryllium, boron, and so on, and we see that there are limits to the number of electrons for each value of $n$. Higher values of the shell $n$ correspond to higher energies, and they can allow more electrons because of the various combinations of $l,\phantom{\rule{0.25em}{0ex}}{m}_{l}$, and ${m}_{s}$ that are possible. Each value of the principal quantum number $n$ thus corresponds to an atomic The probability clouds of electrons with the lowest value of $l$ are closest to the nucleus and, thus, more tightly bound. Thus when shells fill, they start with $l=0$, progress to $l=1$, and so on. Each value of $l$ thus corresponds to a The table given below lists symbols traditionally used to denote shells and subshells. Table 1: Shell and Subshell Symbols
1. It is unusual to deal with subshells having $l$ greater than 6, but when encountered, they continue to be labeled in alphabetical order. To denote shells and subshells, we write $\text{nl}$ with a number for $n$ and a letter for $l$. For example, an electron in the $n=1$ state must have $l=0$, and it is denoted as a $1s$ electron. Two electrons in the $n=1$ state is denoted as $1{s}^{2}$. Another example is an electron in the $n=2$ state with $l=1$, written as $2p$. The case of three electrons with these quantum numbers is written $2{p}^{3}$. This notation, called spectroscopic notation, is generalized as shown in Figure 3. Figure 3 Counting the number of possible combinations of quantum numbers allowed by the exclusion principle, we can determine how many electrons it takes to fill each subshell and shell. Example 1: How Many Electrons Can Be in This Shell?List all the possible sets of quantum numbers for the $n=2$ shell, and determine the number of electrons that can be in the shell and each of its subshells. Strategy Given $n=2$ for the shell, the rules for quantum numbers limit $l$ to be 0 or 1. The shell therefore has two subshells, labeled $2s$ and $2p$. Since the lowest $l$ subshell fills first, we start with the $2s$ subshell possibilities and then proceed with the $2p$ subshell. Solution It is convenient to list the possible quantum numbers in a table, as shown below. Figure 4 Discussion It is laborious to make a table like this every time we want to know how many electrons can be in a shell or subshell. There exist general rules that are easy to apply, as we shall now see. The number of electrons that can be in a subshell depends entirely on the value of $l$. Once $l$ is known, there are a fixed number of values of ${m}_{l}$, each of which can have two values for ${m}_{s}$ First, since ${m}_{l}$ goes from $l$ to l in steps of 1, there are $2l+1$ possibilities. This number is multiplied by 2, since each electron can be spin up or spin down. Thus the maximum number of electrons that can be in a subshell is $2\left(2l+1\right)$. For example, the $2s$ subshell in Example 1 has a maximum of 2 electrons in it, since $2\left(2l+1\right)=2\left(0+1\right)=2$ for this subshell. Similarly, the $2p$ subshell has a maximum of 6 electrons, since $2\left(2l+1\right)=2\left(2+1\right)=6$. For a shell, the maximum number is the sum of what can fit in the subshells. Some algebra shows that the maximum number of electrons that can be in a shell is $2{n}^{2}$. For example, for the first shell $n=1$, and so $2{n}^{2}=2$. We have already seen that only two electrons can be in the $n=1$ shell. Similarly, for the second shell, $n=2$, and so $2{n}^{2}=8$. As found in Example 1, the total number of electrons in the $n=2$ shell is 8. Example 2: Subshells and Totals for $n=3$How many subshells are in the $n=3$ shell? Identify each subshell, calculate the maximum number of electrons that will fit into each, and verify that the total is $2{n}^{2}$. Strategy Subshells are determined by the value of $l$; thus, we first determine which values of $\text{l}$ are allowed, and then we apply the equation “maximum number of electrons that can be in a subshell $=2\left(2l+1\right)$” to find the number of electrons in each subshell. Solution Since $n=3$, we know that $l$ can be $\mathrm{0,\; 1}$, or $2$; thus, there are three possible subshells. In standard notation, they are labeled the $3s$, $3p$, and $3d$ subshells. We have already seen that 2 electrons can be in an $s$ state, and 6 in a $p$ state, but let us use the equation “maximum number of electrons that can be in a subshell = $2\left(2l+1\right)$” to calculate the maximum number in each: $$\begin{array}{l}3s\phantom{\rule{0.25em}{0ex}}\text{has}\phantom{\rule{0.25em}{0ex}}l=0\text{;}\phantom{\rule{0.25em}{0ex}}\text{thus,}\phantom{\rule{0.25em}{0ex}}2\left(2l+1\right)=2\left(0+1\right)=2\\ 3p\phantom{\rule{0.25em}{0ex}}\text{has}\phantom{\rule{0.25em}{0ex}}l=\text{1; thus, 2}\left(2l+1\right)=2\left(2+1\right)=6\\ 3d\phantom{\rule{0.25em}{0ex}}\text{has}\phantom{\rule{0.25em}{0ex}}l=\text{2; thus, 2}\left(2l+1\right)=2\left(4+1\right)=\text{10}\\ \text{Total}=\text{18}\\ (\text{in the}\phantom{\rule{0.25em}{0ex}}n=\text{3 shell})\end{array}$$The equation “maximum number of electrons that can be in a shell = $2{n}^{2}$” gives the maximum number in the $n=3$ shell to be $$\text{Maximum number of electrons}=2{n}^{2}=2{\left(3\right)}^{2}=2\left(9\right)=\text{18.}$$Discussion The total number of electrons in the three possible subshells is thus the same as the formula $2{n}^{2}$. In standard (spectroscopic) notation, a filled $n=3$ shell is denoted as $3{s}^{2}3{p}^{6}3{d}^{\text{10}}$. Shells do not fill in a simple manner. Before the $n=3$ shell is completely filled, for example, we begin to find electrons in the $n=4$ shell. Shell Filling and the Periodic TableTable 2 shows electron configurations for the first 20 elements in the periodic table, starting with hydrogen and its single electron and ending with calcium. The Pauli exclusion principle determines the maximum number of electrons allowed in each shell and subshell. But the order in which the shells and subshells are filled is complicated because of the large numbers of interactions between electrons. Table 2: Electron Configurations of Elements Hydrogen Through Calcium
Examining the above table, you can see that as the number of electrons in an atom increases from 1 in hydrogen to 2 in helium and so on, the lowestenergy shell gets filled first—that is, the $n=1$ shell fills first, and then the $n=2$ shell begins to fill. Within a shell, the subshells fill starting with the lowest $l$, or with the $s$ subshell, then the $p$, and so on, usually until all subshells are filled. The first exception to this occurs for potassium, where the $4s$ subshell begins to fill before any electrons go into the $3d$ subshell. The next exception is not shown in Table 2; it occurs for rubidium, where the $5s$ subshell starts to fill before the $4d$ subshell. The reason for these exceptions is that $l=0$ electrons have probability clouds that penetrate closer to the nucleus and, thus, are more tightly bound (lower in energy). Figure 5 shows the periodic table of the elements, through element 118. Of special interest are elements in the main groups, namely, those in the columns numbered 1, 2, 13, 14, 15, 16, 17, and 18. The number of electrons in the outermost subshell determines the atom’s chemical properties, since it is these electrons that are farthest from the nucleus and thus interact most with other atoms. If the outermost subshell can accept or give up an electron easily, then the atom will be highly reactive chemically. Each group in the periodic table is characterized by its outermost electron configuration. Perhaps the most familiar is Group 18 (Group VIII), the noble gases (helium, neon, argon, etc.). These gases are all characterized by a filled outer subshell that is particularly stable. This means that they have large ionization energies and do not readily give up an electron. Furthermore, if they were to accept an extra electron, it would be in a significantly higher level and thus loosely bound. Chemical reactions often involve sharing electrons. Noble gases can be forced into unstable chemical compounds only under high pressure and temperature. Group 17 (Group VII) contains the halogens, such as fluorine, chlorine, iodine and bromine, each of which has one less electron than a neighboring noble gas. Each halogen has 5 $p$ electrons (a ${p}^{\text{5}}$ configuration), while the $p$ subshell can hold 6 electrons. This means the halogens have one vacancy in their outermost subshell. They thus readily accept an extra electron (it becomes tightly bound, closing the shell as in noble gases) and are highly reactive chemically. The halogens are also likely to form singly negative ions, such as ${\mathrm{C1}}^{}$, fitting an extra electron into the vacancy in the outer subshell. In contrast, alkali metals, such as sodium and potassium, all have a single $s$ electron in their outermost subshell (an ${s}^{1}$ configuration) and are members of Group 1 (Group I). These elements easily give up their extra electron and are thus highly reactive chemically. As you might expect, they also tend to form singly positive ions, such as ${\text{Na}}^{+}$, by losing their loosely bound outermost electron. They are metals (conductors), because the loosely bound outer electron can move freely. Of course, other groups are also of interest. Carbon, silicon, and germanium, for example, have similar chemistries and are in Group 4 (Group IV). Carbon, in particular, is extraordinary in its ability to form many types of bonds and to be part of long chains, such as inorganic molecules. The large group of what are called transitional elements is characterized by the filling of the $d$ subshells and crossing of energy levels. Heavier groups, such as the lanthanide series, are more complex—their shells do not fill in simple order. But the groups recognized by chemists such as Mendeleev have an explanation in the substructure of atoms. PhET Explorations: Build an AtomBuild an atom out of protons, neutrons, and electrons, and see how the element, charge, and mass change. Then play a game to test your ideas! Section Summary
Conceptual QuestionsExercise 1Identify the shell, subshell, and number of electrons for the following: (a) $2{p}^{3}$. (b) $4{d}^{9}$. (c) $3{s}^{1}$. (d) $5{g}^{\text{16}}$. Exercise 2Which of the following are not allowed? State which rule is violated for any that are not allowed. (a) $1{p}^{3}$ (b) $2{p}^{8}$(c) $3{g}^{\text{11}}$ (d) $4{f}^{2}$ Problem ExercisesExercise 1(a) How many electrons can be in the $n=4$ shell? (b) What are its subshells, and how many electrons can be in each? Show/Hide Solution Solution(a) 32. (b) $2\phantom{\rule{0.25em}{0ex}}\text{in}\phantom{\rule{0.25em}{0ex}}s,\phantom{\rule{0.25em}{0ex}}\text{6 in}\phantom{\rule{0.25em}{0ex}}p,\phantom{\rule{0.25em}{0ex}}\text{10 in}\phantom{\rule{0.25em}{0ex}}d,$ and 14 in $f$, for a total of 32. Exercise 2(a) What is the minimum value of 1 for a subshell that has 11 electrons in it? (b) If this subshell is in the $n=\text{5}$ shell, what is the spectroscopic notation for this atom? Exercise 3(a) If one subshell of an atom has 9 electrons in it, what is the minimum value of $l$? (b) What is the spectroscopic notation for this atom, if this subshell is part of the $n=3$ shell? Show/Hide Solution Solution(a) 2 (b) $3{d}^{9}$ Exercise 4(a) List all possible sets of quantum numbers $\left(n,\phantom{\rule{0.25em}{0ex}}l,\phantom{\rule{0.25em}{0ex}}{m}_{l},\phantom{\rule{0.25em}{0ex}}{m}_{s}\right)$ for the $n=3$ shell, and determine the number of electrons that can be in the shell and each of its subshells. (b) Show that the number of electrons in the shell equals $2{n}^{2}$ and that the number in each subshell is $2\left(2l+1\right)$. Exercise 5Which of the following spectroscopic notations are not allowed? (a) $5{s}^{1}$ (b) $1{d}^{1}$ (c) $4{s}^{3}$ (d) $3{p}^{7}$ (e) $5{g}^{15}$. State which rule is violated for each that is not allowed. Show/Hide Solution Solution(b) $n\ge l$ is violated, (c) cannot have 3 electrons in $s$ subshell since $3>(2l+1)=2\phantom{\rule{0.25em}{0ex}}$ (d) cannot have 7 electrons in $p$ subshell since $7>(2l+1)=2(2+1)=6$ Exercise 6Which of the following spectroscopic notations are allowed (that is, which violate none of the rules regarding values of quantum numbers)? (a) $1{s}^{1}$(b) $1{d}^{3}$(c) $4{s}^{2}$ (d) $3{p}^{7}$(e) $6{h}^{\text{20}}$ Exercise 7(a) Using the Pauli exclusion principle and the rules relating the allowed values of the quantum numbers $\left(n,\phantom{\rule{0.25em}{0ex}}l,\phantom{\rule{0.25em}{0ex}}{m}_{l},\phantom{\rule{0.25em}{0ex}}{m}_{s}\right)$, prove that the maximum number of electrons in a subshell is $2{n}^{2}$. (b) In a similar manner, prove that the maximum number of electrons in a shell is 2n^{2}. Show/Hide Solution Solution(a) The number of different values of ${m}_{l}$ is $\pm l,\pm (l1),\text{...,}0$ for each $l>0$ and one for $l=0\Rightarrow (2l+1)\text{.}$ Also an overall factor of 2 since each ${m}_{l}$ can have ${m}_{s}$ equal to either $+1/2$ or $1/2\Rightarrow 2(2l+1)$. (b) for each value of $l$, you get $2(2l+1)$ $=\text{0, 1, 2, ...,}(n\text{\u20131})\Rightarrow 2\left\{\left[(2)(0)+1\right]+\left[(2)(1)+1\right]+\text{.}\text{.}\text{.}\text{.}+\left[(2)(n1)+1\right]\right\}$ $=\underset{\underset{n\phantom{\rule{0.25em}{0ex}}\text{terms}}{\ufe38}}{2\left[1+3+\text{.}\text{.}\text{.}+(2n3)+(2n1)\right]}$ to see that the expression in the box is $={n}^{2},$ imagine taking $(n1)$ from the last term and adding it to first term $=2\left[1+(n\text{\u20131})+3+\text{.}\text{.}\text{.}+(2n3)+(2n1)\u2013(n1)\right]$ $=2\left[n+3+\text{.}\text{.}\text{.}\text{.}+(2n3)+n\right]\text{.}$ Now take $(n3)$ from penultimate term and add to the second term $2\underset{\underset{n\phantom{\rule{0.25em}{0ex}}\text{terms}}{\ufe38}}{\left[n+n+\text{.}\text{.}\text{.}+n+n\right]}={2n}^{2}$. Exercise 8Integrated Concepts Estimate the density of a nucleus by calculating the density of a proton, taking it to be a sphere 1.2 fm in diameter. Compare your result with the value estimated in this chapter. Exercise 9Integrated Concepts The electric and magnetic forces on an electron in the CRT in Section 303 Figure 4 are supposed to be in opposite directions. Verify this by determining the direction of each force for the situation shown. Explain how you obtain the directions (that is, identify the rules used). Show/Hide Solution SolutionThe electric force on the electron is up (toward the positively charged plate). The magnetic force is down (by the RHR). Exercise 10(a) What is the distance between the slits of a diffraction grating that produces a firstorder maximum for the first Balmer line at an angle of $\text{20.0\xba}$? (b) At what angle will the fourth line of the Balmer series appear in first order? (c) At what angle will the secondorder maximum be for the first line? Exercise 11Integrated Concepts A galaxy moving away from the earth has a speed of $\text{0.0100}c$. What wavelength do we observe for an ${n}_{\text{i}}=7$ to ${n}_{\text{f}}=2$ transition for hydrogen in that galaxy? Show/Hide Solution Solution401 nm Exercise 12Integrated Concepts Calculate the velocity of a star moving relative to the earth if you observe a wavelength of 91.0 nm for ionized hydrogen capturing an electron directly into the lowest orbital (that is, a ${n}_{\text{i}}=\infty $ to ${n}_{\text{f}}=1$, or a Lyman series transition). Exercise 13Integrated Concepts In a Millikan oildrop experiment using a setup like that in Section 303 Figure 6, a 500V potential difference is applied to plates separated by 2.50 cm. (a) What is the mass of an oil drop having two extra electrons that is suspended motionless by the field between the plates? (b) What is the diameter of the drop, assuming it is a sphere with the density of olive oil? Show/Hide Solution Solution(a) $6\text{.}\text{54}\times {\text{10}}^{\text{16}}\phantom{\rule{0.25em}{0ex}}\text{kg}$ (b) $5\text{.}\text{54}\times {\text{10}}^{7}\phantom{\rule{0.25em}{0ex}}\text{m}$ Exercise 14Integrated Concepts What doubleslit separation would produce a firstorder maximum at $3\text{.}\text{00\xba}$ for 25.0keV x rays? The small answer indicates that the wave character of x rays is best determined by having them interact with very small objects such as atoms and molecules. Exercise 15Integrated Concepts In a laboratory experiment designed to duplicate Thomson’s determination of ${q}_{e}/{m}_{e}$, a beam of electrons having a velocity of $6\text{.}\text{00}\times {\text{10}}^{7}\phantom{\rule{0.25em}{0ex}}\text{m/s}$ enters a $\text{5.00}\times {\text{10}}^{3}\phantom{\rule{0.25em}{0ex}}\text{T}$ magnetic field. The beam moves perpendicular to the field in a path having a 6.80cm radius of curvature. Determine ${q}_{e}/{m}_{e}$ from these observations, and compare the result with the known value. Show/Hide Solution Solution$1\text{.}\text{76}\times {\text{10}}^{\text{11}}\phantom{\rule{0.25em}{0ex}}\text{C/kg}$ , which agrees with the known value of $1\text{.}\text{759}\times {\text{10}}^{\text{11}}\phantom{\rule{0.25em}{0ex}}\text{C/kg}$ to within the precision of the measurement Exercise 16Integrated Concepts Find the value of $l$, the orbital angular momentum quantum number, for the moon around the earth. The extremely large value obtained implies that it is impossible to tell the difference between adjacent quantized orbits for macroscopic objects. Exercise 17Integrated Concepts Particles called muons exist in cosmic rays and can be created in particle accelerators. Muons are very similar to electrons, having the same charge and spin, but they have a mass 207 times greater. When muons are captured by an atom, they orbit just like an electron but with a smaller radius, since the mass in ${a}_{\text{B}}=\frac{{h}^{2}}{{\mathrm{4\pi}}^{2}{m}_{e}{\text{kq}}_{e}^{2}}=\text{0.529}\times {\text{10}}^{\text{10}}\phantom{\rule{0.25em}{0ex}}\text{m}$ is 207 ${m}_{e}$. (a) Calculate the radius of the $n=1$ orbit for a muon in a uranium ion ($Z=\text{92}$). (b) Compare this with the 7.5fm radius of a uranium nucleus. Note that since the muon orbits inside the electron, it falls into a hydrogenlike orbit. Since your answer is less than the radius of the nucleus, you can see that the photons emitted as the muon falls into its lowest orbit can give information about the nucleus. Show/Hide Solution Solution(a) 2.78 fm (b) 0.37 of the nuclear radius. Exercise 18Integrated Concepts Calculate the minimum amount of energy in joules needed to create a population inversion in a heliumneon laser containing $1\text{.}\text{00}\times {\text{10}}^{4}$ moles of neon. Exercise 19Integrated Concepts A carbon dioxide laser used in surgery emits infrared radiation with a wavelength of $\text{10.6 \mu m}$. In 1.00 ms, this laser raised the temperature of ${\text{1.00 cm}}^{3}$ of flesh to $\text{100\xbaC}$ and evaporated it. (a) How many photons were required? You may assume flesh has the same heat of vaporization as water. (b) What was the minimum power output during the flash? Show/Hide Solution Solution(a) $1\text{.}\text{34}\times {\text{10}}^{\text{23}}$ (b) 2.52 MW Exercise 20Integrated Concepts Suppose an MRI scanner uses 100MHz radio waves. (a) Calculate the photon energy. (b) How does this compare to typical molecular binding energies? Exercise 21Integrated Concepts (a) An excimer laser used for vision correction emits 193nm UV. Calculate the photon energy in eV. (b) These photons are used to evaporate corneal tissue, which is very similar to water in its properties. Calculate the amount of energy needed per molecule of water to make the phase change from liquid to gas. That is, divide the heat of vaporization in kJ/kg by the number of water molecules in a kilogram. (c) Convert this to eV and compare to the photon energy. Discuss the implications. Show/Hide Solution Solution(a) 6.42 eV (b) $7.27\times {\text{10}}^{\text{20}}\phantom{\rule{0.25em}{0ex}}\text{J/molecule}$ (c) 0.454 eV, 14.1 times less than a single UV photon. Therefore, each photon will evaporate approximately 14 molecules of tissue. This gives the surgeon a rather precise method of removing corneal tissue from the surface of the eye. Exercise 22Integrated Concepts A neighboring galaxy rotates on its axis so that stars on one side move toward us as fast as 200 km/s, while those on the other side move away as fast as 200 km/s. This causes the EM radiation we receive to be Doppler shifted by velocities over the entire range of ±200 km/s. What range of wavelengths will we observe for the 656.0nm line in the Balmer series of hydrogen emitted by stars in this galaxy. (This is called line broadening.) Exercise 23Integrated Concepts A pulsar is a rapidly spinning remnant of a supernova. It rotates on its axis, sweeping hydrogen along with it so that hydrogen on one side moves toward us as fast as 50.0 km/s, while that on the other side moves away as fast as 50.0 km/s. This means that the EM radiation we receive will be Doppler shifted over a range of $\pm \text{50}\mathrm{.0\; km/s}$. What range of wavelengths will we observe for the 91.20nm line in the Lyman series of hydrogen? (Such line broadening is observed and actually provides part of the evidence for rapid rotation.) Show/Hide Solution Solution91.18 nm to 91.22 nm Exercise 24Integrated Concepts Prove that the velocity of charged particles moving along a straight path through perpendicular electric and magnetic fields is $v=E/B$. Thus crossed electric and magnetic fields can be used as a velocity selector independent of the charge and mass of the particle involved. Exercise 25Unreasonable Results (a) What voltage must be applied to an Xray tube to obtain 0.0100fmwavelength Xrays for use in exploring the details of nuclei? (b) What is unreasonable about this result? (c) Which assumptions are unreasonable or inconsistent? Show/Hide Solution Solution(a) $1\text{.}\text{24}\times {\text{10}}^{\text{11}}\phantom{\rule{0.25em}{0ex}}\text{V}$ (b) The voltage is extremely large compared with any practical value. (c) The assumption of such a short wavelength by this method is unreasonable. Exercise 26Unreasonable Results A student in a physics laboratory observes a hydrogen spectrum with a diffraction grating for the purpose of measuring the wavelengths of the emitted radiation. In the spectrum, she observes a yellow line and finds its wavelength to be 589 nm. (a) Assuming this is part of the Balmer series, determine ${n}_{\text{i}}$, the principal quantum number of the initial state. (b) What is unreasonable about this result? (c) Which assumptions are unreasonable or inconsistent? Exercise 27Construct Your Own Problem The solar corona is so hot that most atoms in it are ionized. Consider a hydrogenlike atom in the corona that has only a single electron. Construct a problem in which you calculate selected spectral energies and wavelengths of the Lyman, Balmer, or other series of this atom that could be used to identify its presence in a very hot gas. You will need to choose the atomic number of the atom, identify the element, and choose which spectral lines to consider. Exercise 28Construct Your Own Problem Consider the Dopplershifted hydrogen spectrum received from a rapidly receding galaxy. Construct a problem in which you calculate the energies of selected spectral lines in the Balmer series and examine whether they can be described with a formula like that in the equation $\frac{1}{\lambda}=R\left(\frac{1}{{n}_{\text{f}}^{2}}\frac{1}{{n}_{\text{i}}^{2}}\right)$, but with a different constant $R$.
